Why Are Organic Compounds White?

white powder in mason jar ftloscience post

Someone commented on one of our Instagram posts that the only reason they had studied chemistry was because of the ‘amazing colors’. While this is a pretty solid motivation for many of us, an organic chemist might find it harder to relate; most small organic molecules take the form of a white powder or colorless crystals. For a science that is known to be filled with color, we take a look at why some of these compounds refuse to conform.

What Really Is Color?

In order to understand the absence of color in organic compounds, we have to first define color. From a human’s perspective, we perceive color when photons reach our cone cells – these are types of receptors in our eyes that in turn produce signals for our brain to identify different colors. Photons, in this case, can be defined as tiny ‘packets’ of energy, with a corresponding wavelength that is inversely proportional to its energy (i.e. lower energy = bigger wavelength).

Light from the sun is made up of photons that possess many different wavelengths across the electromagnetic spectrum. Some of these correspond to the colors we see, while others aren’t even visible to the human eye, such as infrared, ultraviolet and even X-rays. The photons with wavelengths that correspond to visible colors (between 380 and 780 nm1) combine to produce the sunlight that we all know and love. The sun emits yellow photons at the highest intensity, which is why sunlight isn’t completely white.

Our atmosphere helps this along by scattering shorter wavelengths of visible light (violet and blue); longer wavelengths like yellow pass through unhindered. (This also sort of explains the color of our blue sky!) How light is actually created–well converted, because energy–in the sun involves blackbody radiation when something is heated to a certain temperature, but that’s a topic for another day.

colorful grid sun radiation spectrum
This collage by NASA comes from photos taken by detectors that each pick up specific wavelengths of light from the sun. It is also the origin of the disco ball (don’t quote me).

How Is Color Produced?

How does this white light make objects appear colorful? The myriad of colors that we observe in our everyday lives comes from… electrons! When a molecule is struck by photons, its electrons may decide to move up an energy level or two, depending on the photon’s energy.

If the photon has sufficient energy (i.e. correct wavelength), it can ‘kick’ a molecule’s electron up its energy level. The energy required to do so is specific for every molecule, influenced by its orbitals.

Once an electron is kicked up an energy level it really wants to move back down to its chill ground state, by losing energy in the form of a photon. Through a series of steps, the molecule emits a photon of a single wavelength. If the photon possesses a wavelength that falls within the visible region, we see this as color. These compounds are known as ‘fluorescent’ compounds!

color chart

Light Absorption in Organic Compounds

White powders look white because when light hits these molecules, they are scattered at all angles without being absorbed. In their crystalline form, this light simply passes through —again, without being absorbed—rendering them transparent. For a compound to possess color, some form of light absorption must occur.

It turns out that for smaller molecules, visible light just doesn’t carry enough energy to ‘kick’ its electrons up their energy levels. We can blame this on molecular orbitals and how smaller molecules have a larger energy level gap that needs to be overcome for an electron to be kicked up.

Organic compounds are usually small molecules, usually requiring higher energy light in the ultraviolet range, which is why our eyes don’t pick up on their transitions.

Double Bonds = Color

Hang on, so if I decrease this energy gap and therefore the energy required to excite electrons, maybe visible light could excite my compound? Exactly!

A way to reduce the energy is to introduce double bonds; C=C double bond electron orbitals are higher in energy than their C-C single bond counterparts. Even better would be to conjugate these double bonds so that they absorb energy at an even higher wavelength.

energy gaps of small molecules
Transition energies of some small molecules; lower wavelength = higher energy. As we increase size and conjugation, this energy decreases. Note that the human eye can only pick up transitions above 380 nm. (Biewer, M.C.)

Size Matters Too!

You could also make your compound very big. How does this work? From a molecular orbital perspective, solving Schrodinger’s equation for an ‘electron in a box’ (a great pastime, by the way) gives:

Here’s one I did earlier. Maybe.

Notice that increasing the size L of the ‘box’ (the molecule in this case), leads to a smaller value for energy E. With small organic molecules, E is high because L is small. To put it simply: mashing many orbitals together by increasing the size of a molecule will lower the overall energy, allowing the highest energy electron to transition more easily!

Indeed, many dyes that we use today are structured both conjugated and large, meaning that visible light is enough to make them show off their pretty colors. And yup, they’re actually classified as ‘organic’ dyes.

lucifer yellow
A typical organic dye with an atypical name. Fancy a guess?

While organic chemistry mostly deals with smaller elements such as carbon and nitrogen, transition metals are much larger and contain more electrons. On the other side of the spectrum (ha!), inorganic chemists get to spend their days running out of colors to label their compounds with. Chartreuse, anyone?

Transition metal complexes completely fill up the low-energy orbitals and move into higher-energy ones, allowing their electrons to transition with a whole range of beautiful colors!

green and blue solutions unknown
‘I woke up like this.’


  1. Lapedes, D. N. (1976). Dictionary of Scientific and Technical Terms McGraw-Hill.
  2. Sklar, A. L. (1937). Theory of color of organic compounds. The Journal of Chemical Physics5(9), 669-681.

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2 Responses

  1. Sean says:

    It is indeed 🙂

  2. Shannon says:

    Is it Lucifer Yellow?

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